Re: Clearing Gum Bichromates

Peter Marshall (petermarshall@cix.compulink.co.uk)
Wed, 10 Jan 96 22:54 GMT

In-Reply-To: <821276855.4420.0@mikeware.demon.co.uk>

>
> Mac asks:
>
> >Perhaps you chemists out there could fill me in on how to tell whether my
> >>prints are clear.
>

> The chemical effect of 'clearing' by (meta)bisulphite is to reduce the
> yellow chromium(VI) of dichromate to chromium(III) which is blue-green and
> much paler by comparison. So the chromium is not removed by the clearing
> agent, just made less visible. It would seem better to wash it out if you
> can. It also seems to me likely that residual dichromate will be slowly
> reduced to chromium(III) by constituents of the paper anyway.
>
> Mike

Possibly any residual dichromate could be reduced by some pigments also -
with perhaps unwanted effects on the image? I used to wash until I thought I
had washed it out, then use a clearing bath, then wash this out. Was I just
obsessive?.

Peter Marshall
petermarshall@cix.compulink.co.uk