Re: Making Ferric Oxalate

Terry King (101522.2625@CompuServe.COM)
20 Oct 96 16:49:50 EDT

Eric

Thank you.

You said:
>Terry, I've used the Dick Stevens formula #2 as well. I've gotten the
>30% peroxide though Artcraft Chemicals. (800) 682-1730. 500ml about $40

There seems to be some restriction on the strength of peroxide that can now be
sold in the UK. Even the ever estimable Aldrich from whom I got my supplies
before will only sell 28.5 although it says 30 % on the container.

>I doubt that the plastic vs. glass did anything.

I was just hoping !

> Heat and bubbles are to
>be expected. Be careful.

I know to be careful. Do you find that you have to add more peroxide than Dick
Stevens suggests ? One seems to need to go adding a few ml at a time for a
long time. He says add until looks it looks like root beer. I had root beer
once in 1964 in North Dakota . I can't remember what it looked like but I am
still trying to forget the taste. But I knew I was OK when the solution turned
green.

>What did you get? Green liquid?

Yes at about twenty per cent solution.
> How are you determining % of ferric?
>weight or specific gravity by way of hydrometer?

Hydrometer first but after that I made a print and that seemed to be agood
enough test. Now all I have is two containers both with a brown precipitate
which is presumably ferrous oxalate under a lot of greeny brown liquid. Dick
says add 50 ml of peroxide. Has he left a nought off ? Maybe I gave up too soon.

Terry