When you breathe you only convert a small proportion of the oxygen in the
air to carbon dioxide. This carbon dioxide will react with the alkali in the
developer reducing the pH very slightly.
I would suggest using an 'air' canister like the one used for cleaning the
negs. These contain one of the freon group compounds (usually HFC134a) which
will displace the air and reduce oxidation.
Keith.
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Keith Dowsett "Variables won't; constants aren't."
E-mail: kdowsett@rpms.ac.uk
WWW: http://kd.rpms.ac.uk/index.html