Re: Mordancage

Peter Marshall (petermarshall@cix.compulink.co.uk)
Mon, 26 Jan 1998 20:50 +0000

In-Reply-To: <9801261548.ZM13703@ir6mws28.mas.eurocontrol.be>
I looked out and posted my old formulae for Mordancage - though I almost
certainly called it etch-bleach - which is its English name - a year or so
back. Try searching the archives for this also.

However you don't need formula. A ferricyanide bleach as used for sepia
toning is followed by a brief wash, then immersion in a warm mixture
containing copper ions and hydrogen peroxide. Concentrations are not too
important, though they - and temperature - will alter the speed of
working. Copper sulphate is often cheaper to buy and works fine. I suspect
the solution I used to take from the shelf was 125g/litre. The peroxide I
used was '20 vol'.

Having etch bleached you can redevelop if you want to get a positive
result but with the dark grey and black missing - just paper base. You can
also use dyes that will absorb into the gelatine and give a flat colour
image. If you etch bleach before fixing the print I think you can then
develop it to give a black everywhere except where the emulsion has been
removed - like a lith effect.

There is (or used to be) a Tetenal kit that gave the same results as etch
bleach - they have a different name for it again though. The chemistry was
different and I think more convenient.

Peter Marshall

On Fixing Shadows and elsewhere:
http://www.people.virginia.edu/~ds8s
Family Pictures, German Indications, London demonstrations &
The Buildings of London etc: http://www.spelthorne.ac.uk/pm/