It's probably calcium borate if you were using tap water. (Calcium borate
is almost insoluble in water, so it precipitates.) A way to prevent this
would be to add a gram of EDTA (any of the sodium salts is OK) per liter;
this will sequester the calcium in the tap water and prevent it from
interacting with the metaborate. Or use distilled water for making up the
solution.
<<sil>>
<silh@iag.net>
<webmaster@psa-photo.org>
Sil Horwitz, FPSA
Technical Editor, PSA Journal
check out <http://www.psa-photo.org>