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Ziatype problem



I have been making Ziatype prints for a few months.

Lately (in the last week or so) I have noticed an orange precipitate when I 
add Sodium Chloroplatinate as a contrast agent.

Does anyone have a guess what is happening?

The mix I use is 6 Ammonium Ferric Oxalate, 4 Lithium palladium chloride, 1 
gold chloride, 1 Sodium Chloroplatinate, 1 hydrogen peroxide.

Thanks.

Joe