Re: Silver Nitrate solubility

Chico Seay (cseay@TUblue.pa.utulsa.edu)
Tue, 30 Aug 94 11:30:21 CDT

>
>
> >A question for anyone who can answer it. I made a 10% silver nitrate
> >solution, but the silver doesn't seem to have fully disolved. Is it
> >supposed to? Or do I just shake it up before I use it (I doubt it.)
> >I haven't read a single thing about making the silver solution, so
> >it must be extremely simple. But I'm still confused.
> >
> >Thanks,
> >Adam
>
> The Handbook of Chemistry and Physics has a table of the solubility of
> silver nitrate. According to it, you could have up to a 40% solution! 10%
> by weight would be 10 g of silver nitrate per 100 g of water (or,
> essentially, 100 ml of water). Thorough mixing may be necessary - rocking
> (inverting) the closed container several times should help. Maybe there is
> some impurity in your solid silver nitrate. If that is the case you might
> want to let the solid settle and decant the liquid into another container.
> Use a brown bottle, of course, because of the light sensitivity.
>
> John Bordley
>
>
>
This is my first posting to ANY list, so please please bear
with me if I err in any way.

I am guessing here, but if Adam used tap water instead of
distilled water, any chlorides in the tap water will result in
a milky silver nitrate solution, due to the formation of silver
chloride. My source (Robinson and Abney, "The Art and Practice
of Silver Printing", 1881) recommends that if this is the case,
it must be filtered out, although I do not know what that means.

Now a question I have about a silver nitrate solution is
that the stuff I have read recommends that the solution be heated
(about 100 degrees F) before use. Any comments on the necessity
of this?

Chico Seay