Re: ferri sesquichlorati
Hi :-) have had some interest in sesquichloride of iron
Here with pigmented gelatine, roughly after "The Silver Sunbeam" recipe, too
thick layer of gel - sharpness bad. Positive process, I had no luck with
gum, but did not try very hard...
Sensitivity pretty low, this is 30 minutes exposure with a 2kw metal halide
bulb at 75 cm. The white parts are the exposed areas Thick layer is partly
to blame for the low sensitivity.
http://www.deviantart.com/deviation/33790868/?qo=1&q=by%3Ahalvor+in%3Ascraps
&qh=sort%3Atime
Copy paste whole link.
I believe there is some connections to the pellet process too and the
Ferro-Gallic...(??) at least chemicals involved are about the same.
http://unblinkingeye.com/Articles/Cyano/cyano.html
If anyone know/understand the chemistry behind this I would be interested...
Have some theories, this process have been a background interest for a
while...
(Combination of ammonium ferric citrate + tartaric acid in gelatine did show
tendencies towards a similar result, that was an accidental mixture.)
Halvor
http://halvor.deviantart.com/
On 10/18/06 8:29 AM, "zphoto@montana.net" <zphoto@montana.net> wrote:
> Thank you, Neil! Yes, this is in a book from 1900, so it is
> an old term. It is a gum process wherein you include this
> in the gum mix! I was going to give it a go. But I guess I
> don't have ferric chloride so it'll have to wait. I do have
> lots of FAC.
>
> Sometimes it is such a pain figuring out how to translate
> old chemistry terms.
> Chris
>
> ----- Original Message Follows -----
> From: NEIL MILLER <nkd.miller@btopenworld.com>
> To: alt-photo-process-l@usask.ca
> Subject: Re: ferri sesquichlorati
> Date: Tue, 17 Oct 2006 15:53:14 +0100
>
>> I think it's the same stuff as in Towler's "The Silver
>> Sunbeam," 1864, as sesquichloride of iron, aka ferric
>> chloride.
>>
>> Regards,
>> Neil.
>>
>>
>> ----- Original Message -----
>> From: "Christina Z. Anderson" <zphoto@montana.net>
>> To: "Alt, List" <alt-photo-process-L@usask.ca>
>> Sent: Tuesday, October 17, 2006 3:17 PM
>> Subject: ferri sesquichlorati
>>
>>
>>> Help! Chemists, what is this "ferri sesquichlorati"?
>>> Ferric ammonium citrate? Ferric oxalate? Potassium
>> ferricyanide??? I think it is a German
>>> word??
>>> Chris