U of S | Mailing List Archive | alt-photo-process-l | RE: solarized gums?

RE: solarized gums?



Hi Katharine,

Apparently I had to use "tinting strength" instead of covering, thanks
for pointing that out. BTW, the pigment I used for that particular test
was same as yours, 15:3. I'm still insisting that it was a lightly
pigmented emulsion though...

Anyway, I want to return to the main/actual subject here: the remedy of
"tonal inversion". You suggest to reduce pigment/gum ratio in the
coating solution as the only remedy to the problem - that's what I'm
objecting to.

http://www.pacifier.com/~kthayer/images/BU.jpg

Your step tablet print above (which looks slightly underexposed to me -
will assume it was correctly exposed to make my point) shows paper white
on steps 5 and 6, then stain in form of tonal inversion. What I
understand from this test is: I shouldn't use a negative density above 5
x 0.15 = log 0.75 (or a density range above 0.75 - adjusting exposure
according to the b+f density difference between the Stouffer tablet and
my actual substrate) for that particular coating mix. As someone
printing with digital negatives, why in earth should I change my coating
mix - if I'm happy with its properties such as color, hue, density,
covering power... and whatnot - instead of making necessary adjustments
in the negative? That is what I don't understand - since the step tablet
test clearly shows me a way to protect / free myself from stain in form
of tonal inversion = to adjust my digital negative's DR according to the
properties of my coating mix.

Reducing the pigment/gum ratio may be a perfect solution in case of
using "in-camera negatives" (in other words; when dealing with fixed DR
/ Dmax values) but it may not be the best remedy for someone using
"digital negatives" and determined to use that particular coating mix
(especially for making one-coat gums). That was my point/objection.

Regards,
Loris.

-----Original Message-----
From: Katharine Thayer [mailto:kthayer@pacifier.com] 
Sent: Wednesday, February 14, 2007 8:02 PM
To: alt-photo-process-l@usask.ca
Subject: Re: solarized gums?


Hi Loris,
Well, this is the amazing and wonderful thing about gum, isn't it,  
that no matter what someone says, other people will come back with  
contrary observations or assertions.   At the same time,  I can only  
speak to what I've observed myself, and that's what my web page  
reflects, is my own observations.

Also, I think it would be useful for anyone following the link you  
gave from the archives to read the entire thread, not just the post  
that's linked.  I would point to:

http://www.usask.ca/lists/alt-photo-process/2005/dec05/0479.htm
http://www.usask.ca/lists/alt-photo-process/2005/dec05/0507.htm

to give a more expanded perspective on those particular tests.


> I guess we'll agree that the pigment concentration I used on that
> print is not excessive since that is easily judged by the scan ->  
> this is Phtalo Blue; as we all know, this is a dark pigment with  
> immense covering power...

Unfortunately,  your guess is wrong; I wouldn't agree to most of  
those things.  Sorry....

First, I'm not sure how one could tell just by looking at a scan  
whether a particular pigment mix is overpigmented or not, since an  
overpigmented mix doesn't look  different from an optimally pigmented  
(meaning pigmented to full color saturation for gum printing) mix.   
Overpigmented, by my definition, simply means excess pigment added to  
a mix after color saturation is already reached, so obviously more  
pigment after that point isn't going to change the color saturation  
or the value.

Second, I wouldn't say pthalo is a particularly dark pigment.  It's a  
medium blue, no darker in value than ultramarine and not as dark,  
IME, as Prussian. I'm not sure it could be printed much, or maybe  
any,  darker than what you've got there, although I've been trying.   
My stock mix (which I dilute considerably for tricolor work, since to  
use it at full strength would make the tricolor much too dark) prints  
at about the same value as your demonstration print, as far as I can  
tell.

Also,  I wouldn't use the phrase "immense covering power" for phtalo,  
since my understanding of the term "covering power" is that it refers  
to opacity of the paint layer.   Pthalo is actually a very  
transparent pigment;  even at the heaviest concentration possible,  
the layers underneath can easily be seen through the pthalo, which is  
good because it allows the blending and mixing of colors from  
multiple layers.

But while I wouldn't say pthalo has immense covering power, I would  
say  it has immense pigment strength, meaning that a little goes a  
long way.  Like lamp black,  it takes considerably less pigment to  
reach full color saturation than for most pigments, and by extension,  
less pigment to reach an overpigmented state.

I'm printing a series  of tests now, where twice and even three times  
as much pthalo/gum as my stock mix don't print any darker than the  
stock mix,  and all three are about the same color saturation as your  
example.  (But not the same hue.  I wonder if your pthalo is the red  
shade; I use green shade pthalo --PB 15:3-- and mine seems a bit  
greener than yours)

Here's a small page showing a test strip at 3x the pigment  
concentration required for color saturation (in other words, 3x my  
stock mix) which at least by eyeball looks similar in value to the  
test strip you showed yesterday, and which is also essentially the  
same value as a test strip using my stock mix, which is mixed to  
color saturation.  I also show on the same page what my usual mix for  
tricolor looks like, which is something like 1/2 to 1/3 the  
concentration of my stock mix (I can't give exact amount, because I  
don't mix by weight or volume but by eye; I mix to match the color of  
a paint swatch I keep handy for color matching for each pigment and  
particular use)  I didn't upload the entire series of test strips  
because this doesn't seem a huge issue, and my available webspace is  
limited and getting moreso all the time.

http://www.pacifier.com/~kthayer/html/Pthalostrength.htm

As to the immediate question, I haven't been able to produce either  
stain or "tonal inversion" with any of the three pigment  
concentrations (maximum color saturation,  2x maximum color  
saturation, 3x maximum color saturation)  using a number of different  
exposures for each,  so my tests with pthalo today don't support  
either hypothesis (overpigmentation or underexposure) for "tonal  
inversion."  The 3x saturated mix is so pigmented that the hardened  
dried gum layer looks scumbly,and dark deposits of pigment are left  
at the ends of brush strokes,  but I didn't get any flaking with it,  
or any staining, as I said.

By the way,  the term "tonal inversion" isn't mine, and I don't think  
it's a very apt term, which is why I always put quotes around it.   
But it's a term that's been used to describe this phenomenon, so I've  
reluctantly used it to be consistent with others talking about the  
same thing.
Katharine




On Feb 13, 2007, at 12:21 PM, Loris Medici wrote:

> Hi Katharine,
>
> This (as Ilana describes) is no doubt the phenomenon you name
> "tonal inversion". I've read the page that you wrote about this  
> issue again and don't agree with you in:
>
> "...The remedy, of course, the way to eliminate the tonal
> inversion, is simply to reduce the pigment/gum ratio..."
>
> Because I've experienced the same effect with a lightly pigmented
> blue 31-step tablet print before. See:
>
> http://www.loris.medici.name/Gum-Test-01.jpg
>
> The scan doesn't show it well but, to my bare eyes there's
> definitely paper white at steps 18, 19 (and maybe 20) + there's  
> definitely tone (where there shouldn't be) at steps 20+.
>
> I guess we'll agree that the pigment concentration I used on that
> print is not excessive since that is easily judged by the scan ->  
> this is Phtalo Blue; as we all know, this is a dark pigment with  
> immense covering power...
>
> Regards,
> Loris.
>
> --------
>
> Hi Ilana,
> My own experience, observations and tests don't support the notion
> that failure to clear (aka pigment stain) is a function of  
> underexposure, so I wouldn't agree with your tentative conclusion  
> that "parts that should clear are not, because they have not  
> received enough light." If you're interested, some test strips  
> showing the lack of relationship I found between stain and exposure  
> are here:
>
> http://www.pacifier.com/~kthayer/html/stainexposure.html
>
> It sounds like what is happening to your highlights, if I
> understand the description accurately, is a phenomenon some people  
> call "tonal inversion." For my take on this phenom, see
>
> http://www.pacifier.com/~kthayer/html/tonalinversion.html
>
> Hope any of that is useful to you,
> Katharine
>
>