U of S | Mailing List Archive | alt-photo-process-l | Re: Glycerol as humectant for POP Pd prints at low RH

Re: Glycerol as humectant for POP Pd prints at low RH



----- Original Message ----- 
From: "Loris Medici" <mail@loris.medici.name>
To: <alt-photo-process-l@usask.ca>
Sent: Sunday, February 25, 2007 10:18 PM
Subject: Glycerol as humectant for POP Pd prints at low RH


> Hi all,
>
> Probably I'm not the only smart person to tried this before but since
> I haven't found a reference in the list archives, I decided to share:
>
> I was having hard time making cold/neutral toned POP Pd prints lately;
> the RH of my darkroom changes around 25-30% and printing w/o drying
> thoroughly (in other words: with almost wet paper) isn't a good choice
> since I'm using a relatively weak digital negative substrate and
> printing on almost-wet paper = ruining the negative due excess
> humidity. (The negative substrate I use is Ultrafine Crystal Clear.) I
> also don't prefer to use a thin (1-3 mils) polyester sheet between the
> negative and the paper because sharpness will suffer... (I'm printing
> using a 11x14" contact printing frame and a bank of BL tubes.)
>
> Anyway, given the above criteria, I decided to put glycerol
> (glycerine) into my coating solution. Since this compound is used as a
> humectant in both carbon printing (tissue will retain humidity when
> some glycerol is present and won't brittle) and silver-gelatine
> emulsion making, I thought it may help me in retain humidity in the
> paper -> letting me get cold/neutral tones.
>
> It works! I added a drop of glycerol per 10 drops of coating solution,
> dried the paper for 10 minutes and got a neutral print. Without the
> glycerol - keeping all other parameters constant - I would get a warm
> (brown) print.
>
> Do you think adding glycerol will affect longevity? I'm using very
> little... (0.1ml per 1ml coating solution)
>
> Regards,
> Loris.

In the context of DCG (gelatin) adding glycerol is said to speed up
dichromate reduction. Hence it will accelerate dark reaction.

Martin