effect of hardener on paper


Luis Nadeau (nadeaul@nbnet.nb.ca)
Tue, 19 Jan 1999 16:25:56 -0400


>>- Wayde
>> (wallen@boulder.nist.gov) wrote

>>On Fri, 15 Jan 1999, Tom Ferguson wrote:
>>
>>> I have an interest in hand made paper making. I've never managed to
>>> integrate it with my photography, but it is wonderfully fun and peaceful
>>> pursuit in it's own right. I'm far from an expert. But, all the paper
>>> making literature I've read indicates that Alum is not a good size if
>>> archival properties are important to you. Over time (how long I don't
>>> know) it is said to cause hardening and yellowing.
>>
>>We had a discussion about this about three years ago on the list, and you
>>should be able to locate it in the archives. Luis Nadeau also talks about
>>using Alum and other hardeners in his book on Carbon printing. The thing
>>that sticks in my mind from these discussions is that the use of Alum
>>probably doesn't much affect the archival properties of the paper if it
>>has been sufficiently washed. If I remember correctly, Luis notes in his
>>book that many very old carbon prints were hardened in Alum with
>>apparently not ill affect. (Please correct me if I'm remembering this
>>incorrectly.)

That's correct. Old carbon prints, as a rule, are in much better shape than
everything else, including platinum prints, for reasons elaborated in my Pt
book.

>>I'm curious, does anyone know the long term effects of glyoxal on paper?

It's been used for decades in the photographic industry. I first read about
it when studying Pierre Glafkidès' _Chimie et physique photographique_ in
1976. The previous edition may have had it as well. The effect should be
the same as formaldehyde.

Luis Nadeau
Fredericton, NB, Canada



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