Dichromate Disposal

Judy Seigel (jseigel@panix.com)
Sat, 1 Jul 1995 03:07:04 -0400 (EDT)

Greetings to the chemically inclined:

Having about an ounce of 26% ammounium dichromate to dispose of
in an environmentally responsible manner, & having read contributions to
this list about adding strong alkali & filtering.......

I added an equal quantity of household ammonia, which made no impression,
except for the perfume. (I know household is only 4 or 5% but I was trying to
get rid of it because it made prints smell like low-grade bordello.)

Next I added maybe a tablespoon of sodium carbonate. This foamed up, like
orange sherbert, and was still bright orange, which I took to mean it still
possessed hexavalency. I couldn't find litmus paper, but it was about pH 6
on Hydrion paper.

So I added about 2 teaspoons sodium hydroxide -- all, remember, for an
ounce of original solution. At this point the test color didn't match
any of the squares on the chart. The difference on the chart from 6.5 to 8
was pretty indistinguishable anyway (maybe it faded?).

Anyway, I decided to wait for precipitation to happen, & indeed soon
there was a thin ring of brownish sludge & the rest of the solution
became a dirty, rather watery-looking orange. This I propose to now
filter, sloshing it down the drain, then wiping the sludge out of the
container with a paper towel for future disposal.

The reason I describe all this is that I can't imagine treating say,
a gallon, if it took a proportionate amount of chemical -- which would
simply substitute one problem for another (& probably burn holes in my
pipes).

Maybe it works better if you have used developer to mix it with? (I
didn't have any on hand.)

Any comments/advice would be cherished.

Judy