Sodium bisulfite is NOT an alkali. The pH of a solution of sodium
bisulfite should be about 5. Since most tap water has a pH of about 5, one
would say the sodium bisulfite was essentially neutral. If you had tap
water of pH = 7, then the solution would be slightly acidic. Sodium
sulfite would be basic, with a pH of around 9 or 10.
I checked with a retired chemistry friend who has an interest in the
history of chemistry, and he didn't know of sodium sulfite ever being a
household cleaner. He doubted it, because the sodium sulfite is rather
toxic.
John L. Bordley, Jr.
Department of Chemistry
The University of the South
735 University Ave.
Sewanee, TN 37383-1000
615-598-1801