On Mar 30, 2006, at 12:39 PM, Loris Medici wrote:
> I assumed development of each layer will take 30 minutes. (I had
> developed my tests on paper for 1 hour - I expose "a la Christina"; at
> least 6 minutes - making relatively sturdy layers...) How do you  
> develop
> so quickly? (Hot water, abrading w/ paint pad or brush, water
> jets...???)
>
Sorry, that was a mental lapse; I was thinking of something else when  
I wrote that.  I was thinking about a project I'd done that I  
described here recently, where I was coating yupo with pigmented  
dichromated gum,  and doing two layers from coating of the first  
layer through final dry of the second layer in less than 15 minutes.  
BUT, the crucial thing there was that it didn't involve an image;  
there was only one value: DMax (for that particular pigment mix)  so  
there was nothing to develop, and it only had to be in the water long  
enough to wash out the remaining unreacted dichromated, which really  
only took a couple or three  vigorous swishes through the water.  The  
gum layer was totally hardened after a few seconds in direct sun, so  
there wasn't any soluble gum/pigment left in the layer to be  
developed out. So, sorry, bad example. Yes, when you figure in  
developing an image, it would be more like an hour and 45 minutes  
than 30 minutes to make a tricolor gum on yupo. Like I said, a slight  
brain malfunction. sorry.
But I must take some mild issue with your statement "I expose ala  
Christina, at least 6 minutes-- making relatively sturdy layers." The  
exposure time required to make "relatively sturdy layers" is a  
function of so many things (light source, negative, type of  
dichromate and concentration thereof, and relative humidity, for  
starters) that it is simply meaningless to state an absolute exposure  
time that will result in "relatively sturdy layers."
  My exposure times are almost never more than 2 or 3 minutes, but my  
gum layers are extremely sturdy; I've demonstrated this by pouring  
boiling water on them from a height without disturbing the hardened  
gum. But I use saturated ammonium dichromate and I live in a very  
humid climate, which together probably account for most of the fact  
that I can print a very sturdy layer in a short time.  If I were  
using potassium dichromate, or diluted ammonium dichromate, or if I  
were living in a drier climate, exposure times to make a sturdy layer  
would be longer (and in fact my times are longer during rare dry  
spells here.  So, like I say, a statement to the effect "I expose x  
minutes, making a relatively sturdy gum layer" is a meaningless  
statement.  With some lights, with some dichromates, in some  
environments, 6 minutes would cook the emulsion to a fare-thee-well,   
while with a very different combination, 6 minutes wouldn't be nearly  
enough to create a sturdy gum layer, and 20 minutes might more like  
it. So, it all depends.
>
> I don't see why dichromated PVA wouldn't adhere to Yupo - I mean when
> thinking it is used to "glue" things. (Bookbinding, package
> manufacturing, self adhesive labels...) Of course I'm speculating
> assuming PVA will be more adhesive than (or equally adhesive as) whole
> egg (read as temperapring - I know temperaprinters can make as much  
> as 9
> layers).
>
>
Loris, I didn't ask if you thought it should work, I asked if you  
knew anyone who had done it. But I think maybe a couple of things are  
being confused here.  As to coating, I can coat yupo with gum easily;  
the issue for me with gum and yupo isn't the adhesion of the coating  
to the yupo but the adhesion of the hardened gum to the yupo, which  
is a completely different issue. (Note: I'm talking about a normal  
gum coat, not the extremely thin dry coats that I recently discovered  
adhere very well to yupo through development but are difficult to  
coat smoothly. Whereas a normal gum coat, in my experience, can be  
coated quite smoothly but won't stick to the yupo through development).
Katharine
Received on Thu Mar 30 18:44:31 2006
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